Electrochemistry of Lipophilic Redox Enzymes Associated with a Reversible Follow‐up Chemical Reaction – Theoretical Consideration in Cyclic Staircase Voltammetry

Protein-film voltammetry (PFV) is established as an efficient methodology for studying the redox activity of lipophilic proteins and enzymes some 25 years ago. Yet it still a challenge to understand specific behaviour these systems under different voltametric conditions. In this work we apply cyclic staircase study theoretically electrochemical properties enzymes, whose product transformation at working electrode involved in reversible chemical reaction. Attention paid how kinetics follow-up reaction affects features theoretical cyclo-voltammetric patterns enzymes.